Year: 2015
Type: article
Abstract: 2-Propoxythioxanthen-9-one (1), 2-chloro-4-methylthioxanthen-9-one (2) and tributylstannyloxythioxanthene (3) were reduced to 2-propoxythioxanthen (1′), 2-chloro-4-methylthioxanthen (2′) and thioxanthen (3′) using dibutyltin chloro hydride. The mechanism of this reaction involving formation of tributylstannyloxythioxanthyl ketyl radical has been suggested by comparison of products of hydrostannation of three studied thioxanthene derivatives.
Source: Cogent Chemistry
Authors: Aneta Kosińska, Wojciech J. Kinart
Institution: University of Łódź
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: diamond
OpenAlex ID: W1541917425