Dynamics and mechanisms of hot chemistry stimulated by recoil methods. Progress report, 1 March 1979-29 February 1980. [Silylation of SO/sub 2/ by hexamethyldisilazane]
Year: 1979
Type: report
Abstract: The secondary excitation function for production of cyclobutane-t from the hot hydrogen replacement reaction with cyclobutane was estimated and reported. Using a stepladder model the average stepsizes for cascade deactivation by several bath gases have been determined. Further progress on the interpretation of the dynamics which follow hot chlorine replacement reactions in small ring compounds has also been made. A new silylation reaction with sulfur dixoide was discovered. The process involves the direct attack of hexamethyldisilazane on sulfur dioxide leading eventually to 1,1,1-Trimethyl-N-sulfinyl silanamine.
DOI: 10.2172/5269357
Author: L D Spicer
Language: English
Subfield: Physical and Theoretical Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: green
OpenAlex ID: W240951122