Work

Recent Advances in Transition‐Metal‐Free Oxygenation of Alkene C=C Double Bonds for Carbonyl Generation

Year: 2016

Type: review

Abstract: Carbonyl-forming reactions are a class of fundamental transformations in organic chemistry. Guided by the current importance of environmentally benign metal-free catalysis and synthesis, herein we review recent advances in carbonyl-generation reactions based on alkene C=C double oxygenation as well as related cascade reactions in the synthesis of diverse organic products. The content of this focus review consists of two important but different reaction models: oxygenation based on full C=C double-bond cleavage and oxygenation based on partial C=C double-bond cleavage.

Source: Chemistry - An Asian Journal

DOI: 10.1002/asia.201600671

Authors: Jie‐Ping Wan, Yong Gao, Li Wei

Institution: Jiangxi Normal University

Language: English

Topic: Oxidative Organic Chemistry Reactions

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

Funders: National Science Foundation, National Natural Science Foundation of China

Award: 基于烯胺酮碳-碳双键剪切活化的串联反应研究