Work

UV-Vis Spectral Changes in the Binding of Acyclic Diamines with a Zinc Porphyrin Tweezer

Year: 1998

Type: article

Abstract: Department of Chemistry, Columbia University, New York City, NY, 10027, U.S.A. Manuscript received 18 August 1998 Porphyrin tweezer 1 forms 1:1 complexes with a series of acyclic aliphatic α,.ω-diamines. Chain elongation of the diamines is accompanied by a red-shift in UV -vis maxima and increase in half band-widths of the So ret bands. These changes are accounted for, respectively, by a decrease in exciton coupling and an increase in structural flexibility.

Source: Zenodo (CERN European Organization for Nuclear Research)

DOI: 10.5281/zenodo.5917195

Authors: XUEFEI HUANG, BABAK BORHAN, NINA BEROVA, KOJI NAKANISHI

Language: English

Topic: Porphyrin and Phthalocyanine Chemistry

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: green

Funder: National Institutes of Health

Award: G9000141666

OpenAlex ID: W2527304792

FWCI: 0.303

Cites:

Cited by: 11

Related to: 10