Work

N-Heterocyclic carbene-catalyzed oxidative [3 + 2] annulation of dioxindoles and enals: cross coupling of homoenolate and enolate

Year: 2016

Type: article

Abstract: The N-heterocyclic carbene-catalyzed oxidative [3 + 2] annulation of dioxindole and enals was developed, giving the corresponding spirocyclic oxindole-γ-lactones in good yields with high to excellent diastereo- and enantioselectivities.

Source: Chemical Science

DOI: 10.1039/c6sc04135c

Authors: Xiang-Yu Chen, Kun-Quan Chen, De-Qun Sun, Song Ye

Institutions: Chinese Academy of Sciences, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, University of Chinese Academy of Sciences, Shandong University

Language: English

Topic: N-Heterocyclic Carbenes in Organic and Inorganic Chemistry

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: National Natural Science Foundation of China, Chinese Academy of Sciences

Awards: 基于自由基中间体的卡宾催化反应, G4977143702, G7461813816, G968564448

OpenAlex ID: W2553736986

FWCI: 7.476

Cites: 74

Cited by: 163

Related to: 10