Physiochemical properties of n-n heterostructured TiO 2 /Mo-TiO 2 composites and their photocatalytic degradation of gaseous toluene
Year: 2017
Type: article
Abstract: The composite TiO2/Mo-TiO2 were prepared by a modified sol-gel method. The prepared catalysts were characterized by X-ray diffraction, BET analysis, SEM, X-ray photoelectron spectroscopy, and UV–vis diffused reflectance spectroscopy techniques. The structural characterization results demonstrated that Mo was successfully doped into the TiO2 lattice and caused slight changes in the physiochemical properties. The UV–vis DRS showed a red shift of the adsorption edge to the visible region. The photocatalytic decomposition efficiencies of the catalysts were examined with toluene as a typical VOC in a continuous flow reactor. The photocatalytic activity of the n-n heterogeneous TiO2/Mo-TiO2 was greater than that of pure TiO2 and Mo-TiO2, and the catalyst containing a Mo/Ti mole ratio of 2.5% exhibited optimum photocatalytic properties. In general, a relative humidity of 35%, a higher oxygen content, a lower initial toluene concentration, and a higher UV intensity were beneficial for toluene decomposition.
Authors: Mifen Cui, Shuai Pan, Zhe Tang, Xian Chen, Xu Qiao, Qi Xu
Language: English
Field: Energy
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $1,270
Award: G2533308953
OpenAlex ID: W2605645604