Inside Back Cover: Adamantylidene Addition to M3N@Ih‐C80 (M=Sc, Lu) and Sc3N@D5h‐C80: Synthesis and Crystallographic Characterization of the [5,6]‐Open and [6,6]‐Open Adducts (Chem. Eur. J. 27/2017)
Year: 2017
Type: article
Abstract: Adamantylidene (Ad) additions to endofullerenes M3N@Ih-C80 (M=Sc, Lu) and Sc3N@D5h-C80 are described. Notably, two Ad added bis-adducts of Lu3N@Ih-C80 were obtained, of which the structure of one isomer was determined by X-ray crystallography. The experiments showed that the second Ad addition took place at a position close to an internal Lu atom, thus indicating that the regiochemistry of exohedral additions is influenced by the encaged cluster. More information can be found in the Full Paper by M. M. Olmstead, A. L. Balch, S. Nagase, T. Akasaka et al. on page 6552 ff.
Source: Chemistry - A European Journal
Institutions: Tokyo Gakugei University, University of Tsukuba, Life Science Center for Survival Dynamics, Tsukuba Advanced Research Alliance (TARA), National Chung Cheng University, Charles University, Josai University, Heilongjiang University, State Key Laboratory of Materials Processing and Die & Mould Technology, Huazhong University of Science and Technology, University of California, Davis, Fukui Institute for Fundamental Chemistry, Kyoto University, Foundation for Advancement of International Science
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: bronze
OpenAlex ID: W2613696840