Correlation between Temperature Setting and DCS Complex Peak Energy and in ROMP of Dicyclopentadiene
Year: 2014
Type: article
Abstract: Polydicyclopentadiene is one of the most interesting advanced polymers. After ring open metathesis polymerization (ROMP) by using second generation Grubbs catalyst, we obtain a crosslinked polymer with good mechanical properties. Heating is used to initiate the polymerization process as well as to obtain a higher degree of crosslinking between the polymer chains. We try to analyze the correlation between second stage heating and the degree of cross-linking by using DSC-analysis. DSC analysis shows us a complex exothermic peak after glass transition temperature and this peak area was analyzed.
Source: Procedia Chemistry
Institution: Tomsk Polytechnic University
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: diamond
OpenAlex ID: W1994391613