Work

Changes in Electronic Structure upon Li Deintercalation from LiCoPO 4 Derivatives

Year: 2018

Type: article

Abstract: On the path toward the design of Li-ion batteries with increased energy densities, efforts are focused on the development of positive electrodes that can maximize the voltage of the full cell. However, the development of novel materials that operate at high voltage, while also showing high efficiency and meeting strict safety standards, is an ongoing challenge. LiCoPO 4 is being explored as a possible candidate, as the Co 2+/3+ redox couple operates at 4.8 V versus Li +/ Li 0 . The presence of phosphate groups is typically expected to stabilize the compound against oxygen loss, yet the changes in Co–O bonding upon Li extraction have not been ascertained. In addition, LiCoPO 4 is riddled with problems relating to poor transport and strain in the crystal structure of the delithiated phase, which handicap its use as a high-voltage electrode. In this work, substituting ions to generate Li 1.025 Co 0.84 Fe 0.10 Cr 0.05 Si 0.01 (PO 4 ) 1.025 is found to stabilize both the electronic structure and crystal structure and, therefore, substantially improve the ability to fully utilize the redox capacity of the material. A thorough study by spectroscopic tools, combined with computations of the electronic structure, was used to probe changes in chemical bonding. The measurements revealed the existence of redox gradients between surface and bulk that are common in other materials that react at high potential. The study offers a comprehensive understanding of the fundamental reactions in LiCoPO 4 -type frameworks, while further demonstrating that ion substitution is an effective tool for improving their performance.

Source: Chemistry of Materials

DOI: 10.1021/acs.chemmater.7b04739