Year: 2018
Type: article
Abstract: LiNiO 2 is a promising cathode material for lithium ion batteries because of its high specific capacity (approximately 220 mA h g −1 ). However, there are several challenging issues in the development of LiNiO 2 , including its poor cycle and rate performance because of its structural deterioration due to thermodynamically unstable Ni 3+ . This paper demonstrates the role of Na + in the electrochemical performance and structural stability of [Li 1-x Na x ]NiO 2 (x = 0, 0.005, 0.01, 0.025, and 0.05). Charge disproportionation Ni 3+ → Ni 2+ and Ni 4+ in LiNiO 2 increases the cation mixing of Li + and Ni 2+ during cycling, resulting in the poor cycle performance of LiNiO 2 . However, Na + in [Li 1-x Na x ]NiO 2 mitigates the charge disproportionation because of the larger size of Na + than Li + , leading to the improved structural stability of [Li 1-x Na x ]NiO 2 . Consequently, Na + -doped LiNiO 2 alleviates the increase in the cation mixing of Li + and Ni 2+ during cycling compared to bare LiNiO 2 . This results in the improved cycle performance of [Li 1-x Na x ]NiO 2 (x = 0.05), such as approximately 76% of capacity retention after 100 cycles. Moreover, the substitution of Li + with Na + in LiNiO 2 improves the storage characteristics of [Li 1-x Na x ]NiO 2 , leading to a negligible capacity loss even after long-term storage.
DOI: 10.1149/2.0771802jes
Institution: Seoul National University
Language: English
Subfield: Electrical and Electronic Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: bronze
Awards: G1224826052, G7462307295
OpenAlex ID: W2790272887