Work

Intermolecular Metal-Catalyzed Reductive Coupling of Dienes, Allenes, and Enynes with Carbonyl Compounds and Imines

Year: 2018

Type: review

Abstract: Metal-catalyzed reductive coupling has emerged as an alternative to the use of stoichiometric organometallic reagents in an increasingly diverse range of carbonyl and imine additions. In this review, the use of diene, allene, and enyne pronucleophiles in intermolecular carbonyl and imine reductive couplings are surveyed, along with related hydrogen autotransfer processes.

Source: Chemical Reviews

DOI: 10.1021/acs.chemrev.8b00213

Authors: Michael Holmes, Leyah A. Schwartz, Michael J. Krische

Institution: The University of Texas at Austin

Language: English

Topic: Catalytic Cross-Coupling Reactions

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

Funders: Welch Foundation, National Institute of General Medical Sciences

Awards: G3277079756, Catalytic C-C Bond Forming Hydrogenations