Work

Subsurface catalysis-mediated selectivity of dehydrogenation reaction

Year: 2018

Type: article

Abstract: selectivity was found to increase markedly in the row Pt < PtNi@Pt < PtCo@Pt < PtFe@Pt, which is in line with the calculated trend of d-band center shifting. The established relationship between reactivity and d-band center shifting illustrates the role of subsurface catalysis in dehydrogenation reaction.

Source: Science Advances

DOI: 10.1126/sciadv.aar5418

Authors: Weiting Cai, Rentao Mu, Shenjun Zha, Guodong Sun, Sai Chen, Zhi-Jian Zhao, Hao Li, Hao Tian, Yu Tang, Franklin (Feng) Tao, Liang Zeng, Jinlong Gong

Institutions: Tianjin University, Collaborative Innovation Center of Chemical Science and Engineering Tianjin, University of Kansas

Language: English

Topic: Catalytic Processes in Materials Science

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $4,500

Funders: U.S. Department of Energy, National Natural Science Foundation of China, National Key Research and Development Program of China

Awards: SEE SCHEDULE, G2799079002, G303379125, G4559586091, G4578892347

OpenAlex ID: W2886864778

FWCI: 4.723

Cites: 39

Cited by: 160

Related to: 10