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Enhanced Enantioselectivity in the Fluorescent Recognition of a Chiral Diamine by Using a Bisbinaphthyl Dialdehyde

Year: 2018

Type: article

Abstract: A bisbinaphthyl dialdehyde shows greatly enhanced enantioselective fluorescent response (ef = 10.0) in the fluorescent recognition of a chiral diamine, 1,2-diphenylethylenediamine, over a previously reported monobinaphthyl dialdehyde (ef = 1.1). This compound can be used to determine the enantiomeric composition of the diamine by fluorescence measurement. The NMR and mass spectroscopic studies have demonstrated that the chirality matched reaction of the bisbinaphthyl dialdehyde with the diamine in the presence of Zn(OAc)2 favors the formation of a macrocyclic product more than the chirality mismatched. This enantioselective cyclocondensation should contribute to the observed highly enantioselective fluorescent response because the macrocyclic Zn(II) complex is proposed to give much greater fluorescence enhancement than the acyclic ones.

Source: ACS Omega

DOI: 10.1021/acsomega.8b01870

Authors: Chaoyuan Zeng, Xiaoling Zhang, Lin Pu

Institutions: Beijing Institute of Technology, University of Virginia

Language: English

Topic: Molecular Sensors and Ion Detection

Subfield: Spectroscopy

Field: Chemistry

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $1,935

Funders: National Natural Science Foundation of China, China Scholarship Council, Division of Chemistry