Work

Reversible homolytic activation of water via metal–ligand cooperativity in a T-shaped Ni( ii ) complex

Year: 2018

Type: article

Abstract: , and 2.4(1), respectively. In addition to the reversibility of water addition, this system is capable of activating water towards net O-atom transfer to substrates such as aromatic C-H bonds and phosphines. This reactivity is facilitated by the ability of the dihydrazonopyrrole ligand to accept H-atoms and illustrates the utility of metal ligand cooperation in activating O-H bonds with high bond dissociation energies.

Source: Chemical Science

DOI: 10.1039/c8sc03719a

Authors: Mu-Chieh Chang, Kate A. Jesse, Alexander S. Filatov, John S. Anderson

Institution: University of Chicago

Language: English

Topic: Metal-Catalyzed Oxygenation Mechanisms

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond