Work

Chemically fueled covalent crosslinking of polymer materials

Year: 2019
Type: article
Abstract: Transiently crosslinked dynamic polymer networks are developed, using carbodiimide hydration to link carboxylic acids as anhydrides. From aqueous polymer solutions, non-equilibrium hydrogels are transiently formed, which dissolve upon anhydride hydrolysis. The materials can be refueled using a subsequent injection of carbodiimide. The gels exhibit higher storage moduli compared to transient supramolecular gels as a result of their covalent crosslinks.
Institution: Miami University
Language: English
Open Access status: green
OpenAlex ID: W2909689705
FWCI: 4.331
Cites: 26
Cited by: 84
Related to: 10