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Diiron oxo reactivity in a weak-field environment

Year: 2019
Type: article
Abstract: A dinucleating cofacial Pacman dipyrrin ligand platform was utilized to isolate diiron bridging oxo complexes in a variety of oxidation states. The interplay between oxidation state and acid/base reactivity in diiron μ-oxo units is explored herein.
DOI: 10.1039/c9sc00605b
Institution: Harvard University
Language: English
Field: Chemistry
Open Access status: diamond
Funders: National Science Foundation, Camille and Henry Dreyfus Foundation, Harvard University, European Commission, National Institutes of Health, Horizon 2020 Framework Programme, Horizon 2020, National Institute of General Medical Sciences
Awards: Correlation of electronic structure to iron catalyzed C-H bond functionalization, G1787376792, G2849005763, G2882681475, G434337789, Redox-responsive Magnetic Materials based on Polynuclear Organometallics
OpenAlex ID: W2943959655
FWCI: 0.749
Cites: 47
Cited by: 18
Related to: 10