Work

Tuning ligand field strength with pendent Lewis acids: access to high spin iron hydrides

Year: 2019

Type: article

Abstract: Pendent borane Lewis acids provide an avenue for changing a ligand's field strength through acid/base interactions; this strategy was highlighted within a series of biologically-relevant high spin iron hydrides.

Source: Chemical Science

DOI: 10.1039/c9sc00561g

Authors: John J. Kiernicki, James P. Shanahan, Matthias Zeller, Nathaniel K. Szymczak

Institutions: University of Michigan, Purdue University West Lafayette

Language: English

Topic: Organometallic Complex Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: National Science Foundation, Camille and Henry Dreyfus Foundation, National Institutes of Health, National Institute of General Medical Sciences, Division of Chemistry

Awards: G1124212407, The Role of Secondary Interactions Relevant to Biological Reductions of Small Molecules, MRI: Acquisition of an X-ray Diffractometer at Purdue University, G4267811985, Elucidating the Effects of Secondary Interactions Relevant to Enzymatic Small Molecule Activation

OpenAlex ID: W2944783027

FWCI: 1.862

Cites: 60

Cited by: 34

Related to: 10