Work

Triggering Cu-coordination change in Cu( ii )-Ala-His-His by external ligands

Year: 2019

Type: article

Abstract: Copper(ii) forms well-known and stable complexes with peptides having histidine at position 2 (Xxx-His) or 3 (Xxx-Zzz-His). Their properties differ considerably due to the histidine positioning. Here we report that in the hybrid motif Xxx-His-His, the Cu(ii)-complexes can be switched between the Xxx-His and the Xxx-Zzz-His coordination modes by addition of external ligands.

Source: Chemical Communications

DOI: 10.1039/c9cc03174j

Authors: Paulina Gonzalez, Karolina Bossak-Ahmad, Bertrand Vileno, Nina E. Wezynfeld, Youssef El Khoury, Petra Hellwig, Christelle Hureau, Wojciech Bal, Peter Faller

Institutions: Centre National de la Recherche Scientifique, Institut de Chimie de Strasbourg, Institut de Chimie, Université de Strasbourg, Polish Academy of Sciences, Chimie de la Matière Complexe, Université de Toulouse

Language: English

Topic: Metal complexes synthesis and properties

Subfield: Oncology

Field: Medicine

Domain: Health Sciences

Open Access status: green

Funders: Agence Nationale de la Recherche, Fundacja na rzecz Nauki Polskiej, Université de Strasbourg, Narodowe Centrum Nauki, Ministerstwo Edukacji i Nauki, Centre National de la Recherche Scientifique, Fondation Pour la Recherche en Chimie, LabEx Chimie des Systèmes Complexes, European Research Council

Awards: G255097870, G3286977661, Center of Chemistry of Complex System, G5838517442, G674004797, G7353620968

OpenAlex ID: W2951551012

FWCI: 1.685

Cites: 27

Cited by: 22

Related to: 10