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Cover Feature: Isolation and Crystallographic Characterization of Two, Nonisolated Pentagon Endohedral Fullerenes: Ho3N@C2(22010)‐C78 and Tb3N@C2(22010)‐C78 (Chem. Eur. J. 54/2019)

Year: 2019

Type: article

Abstract: The molecular structure of Ho3N@C2(22010)-C78 is shown in the cover artwork, along with the two molecules of nickel octaethylporphyrin (Ni(OEP) that surround it in the co-crystal, Ho3N@C2(22010)-C78⋅2 Ni(OEP)⋅2 toluene. Ho3N@C2(22010)-C78 contains a planar Ho3N unit surrounded by a chiral carbon cage. That cage violates the isolated pentagon rule by having two sites where two pentagons share a common edge. Color code: nitrogen, blue; holmium, orange; nickel, green; carbon, gray. More information can be found in the Full Paper by S. Stevenson, H. C. Dorn, M. M. Olmstead, A. L. Balch, et al. on page 12545.

Source: Chemistry - A European Journal

DOI: 10.1002/chem.201903331

Authors: Steven Stevenson, Amanda J. Rothgeb, Katelyn R. Tepper, James Duchamp, Harry C. Dorn, Xian B. Powers, Mrittika Roy, Marilyn M. Olmstead, Alan L. Balch

Institutions: Purdue University Fort Wayne, Virginia Tech, University of California, Davis

Language: English

Topic: Fullerene Chemistry and Applications

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

OpenAlex ID: W2975492168

FWCI:

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