Work

Methylene: The Linker of Two Aromatic Iminium Salts

Year: 2019

Type: article

Abstract: A straightforward synthesis of aromatic iminium salts has been developed by coupling 2-Azido-1,3,5-trimethyl benzene with 1,3-ditert-butylimidazolium tetrafluoroborate in basic conditions, followed by treatment with dichloromethane or iodomethane. Herein, we report the synthetic procedure and full characterization data, including X-ray structure analysis, of the expected bis(triazenyl)methane adduct 5. Moreover, we have discovered what constitutes a double carbon-chlorine bond activation.

Source: Journal of the Mexican Chemical Society

DOI: 10.29356/jmcs.v63i3.525

Authors: Anurag Noonikara-Poyil, Enrique Barragan, Siddappa Patil, Alejandro Bugarin

Institutions: The University of Texas at Arlington, Jain University

Language: English

Topic: Organic and Inorganic Chemical Reactions

Subfield: Spectroscopy

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: Florida Gulf Coast University, American Chemical Society Petroleum Research Fund

Award: G2258943442