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Natural Deep Eutectic Solvents as Performance Additives for Peroxygenase Catalysis

Year: 2019

Type: article

Abstract: Natural deep eutectic solvents (NADES) are proposed as alternative solvents for peroxygenase‐catalysed oxyfunctionalization reactions. Choline chloride‐based NADES are of particular interest as they can serve as solvent, enzyme‐stabiliser and sacrificial electron donor for the in situ H2O2 generation. This report provides the first proof‐of‐concept and basic characterisation of this new reaction system. Highly promising turnover numbers for the biocatalysts of up to 200,000 have been achieved.

Source: ChemCatChem

DOI: 10.1002/cctc.201901842

Authors: Yunjian Ma, Yongru Li, Shahid Ali, Peilin Li, Wuyuan Zhang, Marine C. R. Rauch, Sébastien J.‐P. Willot, Doris Ribitsch, Young Hae Choi, Miguel Alcalde, Frank Hollmann, Yonghua Wang

Institutions: South China University of Technology, Delft University of Technology, Austrian Centre of Industrial Biotechnology (Austria), Leiden University, Kyung Hee University, Consejo Superior de Investigaciones Científicas, Instituto de Catálisis y Petroleoquímica

Language: English

Topic: Enzyme Catalysis and Immobilization

Subfield: Molecular Biology

Field: Biochemistry, Genetics and Molecular Biology

Domain: Life Sciences

Open Access status: hybrid

Estimated APC paid: $3,500

Funders: European Commission, Higher Education Discipline Innovation Project, Horizon 2020 Framework Programme, H2020 European Research Council

Awards: New enzymatic oxidation/oxyfunctionalization technologies for added value bio-based products, G390674010, G4266176255, G477451022, G4937468798, Water as cosubstrate for biocatalytic redox reactions

OpenAlex ID: W2986368746

FWCI: 1.145

Cites: 20

Cited by: 36

Related to: 10