Year: 2020
Type: article
Abstract: A novel electro-active shape memory polymer (SMP) was fabricated with fully soluble self-doped poly(3,4-ethylenedioxythiophene) (S-PEDOT) and SMP using a solution mixing method at various S-PEDOT weight ratios ( W S-PEDOT ). The percolation analysis showed an extreme low percolation threshold of 0.38 vol% and critical exponent of 1.15, which was associated with the S-PEDOT conductive networks formed by phase separation in the S-PEDOT:SMP composite. The shape memory characteristics were observed at W S-PEDOT ≤ 30 wt%, while the glass transition temperature ( T g ) was almost constant ca. 50 °C. The S-PEDOT:SMP composite film at W S-PEDOT = 10 wt% showed electrical conductivity ( σ ), shape fixing ratio ( R f ), and shape recovery ratio ( R r ) of 29 S cm −1 , 95.4%, and 90.1%, respectively. Furthermore, an electro-active SMP soft actuator, fabricated using the S-PEDOT:SMP composite film at W S-PEDOT = 10 wt%, quickly recovered from a temporary bent shape to its original open shape within 5 s upon application of 6 V.
Authors: YingJun An, Hidenori Okuzaki
Institution: University of Yamanashi
Language: English
Subfield: Mechanical Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: bronze
OpenAlex ID: W3023581773