Work

Ba2YIrO6 : A cubic double perovskite material with Ir5+ ions

Year: 2016

Type: article

Abstract: Materials with a $5{d}^{4}$ electronic configuration are generally considered to have a nonmagnetic ground state ($J=0$). Interestingly, ${\mathrm{Sr}}_{2}{\mathrm{YIrO}}_{6}$ (${\mathrm{Ir}}^{5+}$ having $5{d}^{4}$ electronic configuration) was recently reported to exhibit long-range magnetic order at low temperature and the distorted ${\mathrm{IrO}}_{6}$ octahedra were discussed to cause the magnetism in this material. Hence, a comparison of structurally distorted ${\mathrm{Sr}}_{2}{\mathrm{YIrO}}_{6}$ with cubic ${\mathrm{Ba}}_{2}{\mathrm{YIrO}}_{6}$ may shed light on the source of magnetism in such ${\mathrm{Ir}}^{5+}$ materials with $5{d}^{4}$ configuration. Besides, ${\mathrm{Ir}}^{5+}$ materials having $5{d}^{4}$ are also interesting in the context of recently predicted excitonic types of magnetism. Here we report a single-crystal-based analysis of the structural, magnetic, and thermodynamic properties of ${\mathrm{Ba}}_{2}{\mathrm{YIrO}}_{6}$. We observe that in ${\mathrm{Ba}}_{2}{\mathrm{YIrO}}_{6}$ for temperatures down to 0.4 K, long-range magnetic order is absent but at the same time correlated magnetic moments are present. We show that these moments are absent in fully relativistic ab initio band-structure calculations; hence, their origin is presently unclear.

Source: Physical review. B./Physical review. B

DOI: 10.1103/physrevb.93.014434