Work

Turning on solid-state phosphorescence of platinum acetylides with aromatic stacking

Year: 2020

Type: article

Abstract: Neat solids that phosphoresce under ambient conditions are rare due to aggregation-caused quenching. This communication describes a platinum acetylide (PtPE) that phosphoresces as a solid due to programmed aromatic stacking interactions of pendant groups that prevent intermolecular aggregation.

Source: Chemical Communications

DOI: 10.1039/d0cc02119a

Authors: William J. Mullin, Huan Qin, Tomoyasu Mani, Peter Müller, Matthew J. Panzer, Samuel W. Thomas

Institutions: Tufts University, University of Connecticut, Massachusetts Institute of Technology

Language: English

Topic: Luminescence and Fluorescent Materials

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: green

Funders: U.S. Department of Energy, Basic Energy Sciences

Awards: CONTROLLING SOLID-STATE PACKING AND PROPERTIES OF CONJUGATED MATERIALS WITH DISCRETE AROMATIC INTERACTIONS OF SIDE CHAINS, G4964592377