Frontispiece: Exceptional Substrate Diversity in Oxygenation Reactions Catalyzed by a Bis(μ‐oxo) Copper Complex
Year: 2020
Type: paratext
Abstract: The tyrosinase-like activity of a new bioinspired bis(μ-oxo) dicopper(III) catalyst was investigated herein. The hybrid guanidine-stabilized catalyst revealed a remarkable oxygenation activity on diverse phenolic substrate classes, products of which were consistently predicted by DFT calculations. The selective C−H activation of mono- and bicyclic substrates provides a new benchmark to future developments on tyrosinase model systems on the route to atom-economic oxygen-transfer reactions. More information can be found in the Communication by S. Herres-Pawlis et al. on page 7556 ff.
Source: Chemistry - A European Journal
Authors: Melanie Paul, Melissa Teubner, Benjamin Grimm‐Lebsanft, Christiane Golchert, Yannick Meiners, Laura Senft, Kristina Keisers, Patricia Liebhäuser, Thomas Rösener, Florian Biebl, Sören Buchenau, Maria Naumova, Vadim Murzin, Roxanne Krug, Alexander Hoffmann, Jörg Pietruszka, Ivana Ivanović‐Burmazović, Michael Rübhausen, Sonja Herres‐Pawlis
Language: English
Subfield: Inorganic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: bronze
OpenAlex ID: W3035925595