Year: 2020
Type: article
Abstract: Differential geometry offers a powerful framework for optimising and characterising finite-time thermodynamic processes, both classical and quantum. Here, we start by a pedagogical introduction to the notion of thermodynamic length. We review and connect different frameworks where it emerges in the quantum regime: adiabatically driven closed systems, time-dependent Lindblad master equations, and discrete processes. A geometric lower bound on entropy production in finite-time is then presented, which represents a quantum generalisation of the original classical bound. Following this, we review and develop some general principles for the optimisation of thermodynamic processes in the linear-response regime. These include constant speed of control variation according to the thermodynamic metric, absence of quantum coherence, and optimality of small cycles around the point of maximal ratio between heat capacity and relaxation time for Carnot engines.
Source: Entropy
DOI: 10.3390/e22101076
Language: English
Subfield: Statistical and Nonlinear Physics
Field: Physics and Astronomy
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $1,690
Funders: “la Caixa” Foundation, Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung, Generalitat de Catalunya, Ministerio de Asuntos Económicos y Transformación Digital, Gobierno de España, Fundación Bancaria Caixa d'Estalvis i Pensions de Barcelona, Engineering and Physical Sciences Research Council
OpenAlex ID: W3082486289
