Halonium Catalysis: An Underutilized and Underexplored Catalytic Concept in Olefin Functionalizations
Year: 2020
Type: article
Abstract: Iodonium catalysis is described here to accomplish an intermolecular olefin oxyamination reaction. Urea is used as the O- and N-source to add across both activated and unactivated alkenes in a regioselective manner. Mechanistic studies confirm the presence of an iodonium intermediate. 1 Introduction 2 Hypothesis 3 Optimizations and Scope 4 Mechanistic Probes 5 Future Outlook
Source: Synlett
DOI: 10.1055/a-1277-8669
Authors: Wei Li, Nathan R. Gembreska, Alexander K. Vogel, Elizabeth C. Ziegelmeyer, Eric Cheng, Fan Wu, Leo P. Roberts, Megan M. Vesoulis
Institution: University of Toledo
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: green
OpenAlex ID: W3090948743