Work

Indirect detection of intermediate in decarboxylation reaction of phenylglyoxylic acid by hyperpolarized 13 C NMR

Year: 2020

Type: article

Abstract: The decarboxylation reaction of phenylglyoxylic acid with hydrogen peroxide is studied by real-time hyperpolarized carbon-13 nuclear magnetic resonance (13C NMR) spectroscopy at room temperature. A non-observable reaction intermediate is identified using blind selective saturation pulses in the expected chemical shift range, thereby revealing information on the reaction mechanism.

Source: Chemical Communications

DOI: 10.1039/d0cc06331b

Authors: Jiwon Kim, Yaewon Kim, Quy Son Luu, Jihyun Kim, Chang Qi, Christian Hilty, Youngbok Lee

Institutions: Hanyang University, Texas A&M University, University of California, San Francisco

Language: English

Topic: Advanced NMR Techniques and Applications

Subfield: Spectroscopy

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

Funders: Korea Research Institute of Standards and Science, Korea Health Industry Development Institute, National Research Foundation of Korea, Ministry of SMEs and Startups, National Institute of General Medical Sciences

Awards: G2625686524, G310758877, Hyperpolarization Assisted and Structure Based Screening of Protein-Ligand Interactions in Live Cells, G4086867055, G4812567097, G6941462951

OpenAlex ID: W3103958758

FWCI: 0.191

Cites: 19

Cited by: 3

Related to: 10