Thermal anisotropy enhanced by phonon size effects in nanoporous materials
Year: 2016
Type: preprint
Abstract: While thermal anisotropy is a desirable materials property for many applications, including transverse thermoelectrics and thermal management in electronic devices, it remains elusive in practical natural compounds. In this work, we show how nanoporous materials with anisotropic pore lattices can be used as a platform for inducing strong heat transport directionality in isotropic materials. Using density functional theory and the phonon Boltzmann transport equation, we calculate the phonon-size effects and thermal conductivity of nanoporous silicon with different anisotropic pore lattices. Our calculations predict a strong directionality in the thermal conductivity, dictated by the difference in the pore-pore distances, i.e., the phonon bottleneck, along the two Cartesian axes. Using Fourier's law, we also compute the diffusive heat transport for the same geometries obtaining significantly smaller anisotropy, revealing the crucial role of phonon-size effects in tuning thermal transport directionality. Besides enhancing our understanding of nanoscale heat transport, our results demonstrate the promise of nanoporous materials for modulating anisotropy in thermal conductivity.
Authors: Romano, Giuseppe, Kolpak, Alexie M.
Institution: Massachusetts Institute of Technology
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: green
Funder: U.S. Department of Energy
Award: G2966269038
OpenAlex ID: W3104135361