Year: 2021
Type: article
Abstract: It is reported that SnSe2 consisting of the same elements as SnSe, is a new promising thermoelectric material with advantageous layered structure. In this work, the thermoelectric performance of polycrystalline SnSe2 is improved through introducing SnSe phase and electron doping (Cl doped in Se sites). The anisotropic transport properties of SnSe2 are investigated. A great reduction of the thermal conductivity is achieved in SnSe2 through introducing SnSe phase, which mainly results from the strong SnSe2–SnSe inter-phase scattering. Then the carrier concentration is optimized via Cl doping, leading to a great enhancement of the electrical transport properties, thus an extraordinary power factor of ∼5.12 μW⋅cm−1⋅K−2 is achieved along the direction parallel to the spark plasma sintering (SPS) pressure direction (∥ P). Through the comprehensive consideration on the anisotropic thermoelectric transport properties, an enhanced figure of merit ZT is attained and reaches to ∼ 0.6 at 773 K in SnSe2-2% SnSe after 5% Cl doping along the ∥ P direction, which is much higher than ∼ 0.13 and ∼ 0.09 obtained in SnSe2-2% SnSe and pristine SnSe2 samples, respectively.
Source: Chinese Physics B
Authors: Caiyun Li, Wenke He, Dongyang Wang, Li-Dong Zhao
Institution: Beihang University
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: bronze
Funders: National Natural Science Foundation of China, Beihang University, Higher Education Discipline Innovation Project, National Postdoctoral Program for Innovative Talents, National Key Research and Development Program of China, Shenzhen Peacock Plan, National Science Fund for Distinguished Young Scholars
OpenAlex ID: W3137765639