Year: 2021
Type: article
Abstract: In here, the nonisothermal decomposition kinetics of co-polymers based phenothiazine was present-ed. For this, firstly, 3, 7-di-2-thienyl-10H-phenothiazine (TF) was prepared via an optimized Suzu-ki–Miyaura cross-coupling reaction. After monomer (TF) characterization, the copolymerization re-actions with EDOT and thiophene were performed by the electrochemical technique. The molecular masses of the co-polymers were found by gel permeation chromatography (GPC) analysis. Thermal characterizations of the resulting polymers were conducted by thermogravimetric analyses. The thermal decomposition kinetics of the resulting polymers was also performed. For this, the kinetic methods (Tang, FWO, KAS, Kissinger, and Friedman) based on the multiple heating rates were used. Several kinetic parameters related to the decomposition kinetics of the solid-state were revealed.
Author: Fatih Dogan
Institution: Çanakkale Onsekiz Mart Üniversitesi
Language: English
Topic: Thermal and Kinetic Analysis
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: diamond
OpenAlex ID: W3151796958