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An evolutionary condensation sequence revealed by mineralogically-distinct nodules in fine-grained, spinel-rich inclusions from CV3 chondrites: Implications for the genetic links between different types of non-igneous refractory inclusions

Year: 2021
Type: article
DOI: 10.1016/j.gca.2021.05.055
Language: English
Open Access status: bronze
Award: THE RESEARCH OUTLINED IN THIS PROPOSAL IS DIRECTED TOWARDS UNDERSTANDING THE NATURE AND ORIGIN OF A VARIETY OF COMPONENTS INCHONDRITIC METEORITES IN THE CONTEXT OF EARLY SOLAR NEBULAR AND PARENT BODY EVOLUTION. THE RESEARCH SPECIFICALLY ADDRESS NASA STRATEGIC GOAL 2 TO `ADVANCE SCIENTIFIC KNOWLEDGE OF THE ORIGIN AND HISTORY OF THE SOLAR SYSTEM AND THE POTENTIAL FOR LIFE ELSEWHERE . THE GOALS OF THE RESEARCH ARE TO UNRAVEL THE COMPLEX SEQUENCE OF EVENTS THAT PRODUCED THE CHEMICALLY AND MINERALOGICALLY DIVERSE ASSEMBLAGES OBSERVED IN PRIMITIVE METEORITES. WE WILL CARRY OUT MINERALOGICAL PETROLOGIC AND ISOTOPIC STUDIES USING A VARIETY OF MICROBEAM TECHNIQUES (SEM EPMA FIB/TEM NANOSIMS AND SXRF MICROPROBE) AS WELL AS STABLE ISOTOPE TECHNIQUES IN A COLLABORATIVE EFFORT WITH SEVERAL OTHER RESEARCH GROUPS. OUR PROPOSED STUDIES ARE DIVIDED INTO FOUR SPECIFIC AREAS: 1) MINERALOGICAL AND STABLE ISOTOPIC STUDIES TO CONSTRAIN AQUEOUS ALTERATION PROCESSES IN CR CHONDRITES 2) MICROSTRUCTURAL AND STABLE ISOTOPIC STUDIES OF AMEBOID OLIVINE AGGREGATES (AOAS) AND CAIS IN CO3 CHONDRITES TO CONSTRAIN THEIR FORMATION AND THERMAL HISTORIES. 3) EPMA AND TEM STUDIES OF METASOMATIC AND METAMORPHIC EFFECTS IN REFRACTORY INCLUSIONS (AOAS AND CAIS) CO3 CHONDRITES 4) TEM AND TRACE ELEMENT STUDIES OF SULFIDES IN CM CHONDRITES TO CONSTRAIN THEIR FORMATIONAL AND THERMAL HISTORIES. FOR RESEARCH TASK 1 WEWILL ALSO EXAMINE THE MINERALOGICAL EVOLUTION OF MATRICES IN CR CHONDRITES AS INDICATORS OF PROGRESSIVE ALTERATION FOCUSING ON THE ROLE OF HYDRATED AMORPHOUS MATERIAL AS AN INDICATOR OF THE INTENSITY OF ALTERATION. THIS WORK WILL INVOLVE COORDINATED FIB/TEM IR NANOSIMS HYDROGEN AND OXYGEN ISOTOPIC ANALYSES TO CONSTRAIN THE PROGRESSIVE ALTERATION OF CR CHONDRITE MATRICES IN MORE DETAIL. WE WILL ALSO STUDY THE MECHANISMS OF HYDRATION OF SILICATE GLASS IN CHONDRULES IN CR CHONDRITES TO CONSTRAIN THE ALTERATION MECHANISM AND PROCESSES OF ELEMENTAL MASS TRANSPORT AND ELEMENTAL AND ISOTOPIC EXCHANGE. FOR RESEARCH TASK 2 WE WILL CARRY OUTCOORDINATED FIB/TEM AND NANOSIMS OXYGEN ISOTOPIC STUDIES OF THE REFRACTORY COMPONENT OF AMEBOID OLIVINE AGGREGATES AND CAIS IN CO CHONDRITES TO CONSTRAIN THEIR FORMATION AND THERMAL HISTORIES. IN PARTICULAR WE WILL FOCUS ON AOAS AND CAIS THAT SHOW EVIDENCE OF COMPLEX THERMAL HISTORIES THAT MAY BE INDICATIVE OF TRANSPORT AND INTERACTION WITH THE GAS PHASE IN DIFFERENT REGIONS OF THE SOLAR NEBULA. A COMPONENT OF THIS WORK WILL INVOLVE THE STUDY OF REFRACTORY METAL NANOPARTICLES WHICH WE HAVE RECENTLY DISCOVERED IN SITU IN AOAS IN CO3 CHONDRITES. THIS EFFORT WILL HELP CONSTRAIN THE POTENTIAL ORIGINS OF REFRACTORY METAL ALLOYS WHICH OCCUR IN OTHER TYPES OF CARBONACEOUS CHONDRITES. FOR RESEARCH TASK 3 WE WILL INVESTIGATE THE DETAILED RESPONSE OF CAIS AND AOAS IN CO3 CHONDRITES TO THERMAL METAMORPHISM AND METASOMATISM USING SEM EPMA AND FIB/TEM IN ORDER TO DEVELOP A MORE THOROUGH UNDERSTANDING OF THE INTERRELATIONSHIPS BETWEEN THESE TWO PROCESSES AND CONSTRAIN THE ROLE OF FLUIDS IN THE ALTERATION PROCESSES. FOR RESEARCH TASK 4 WE WILL PERFORM COORDINATE SEM EPMA FIB/TEM AND SXRF STUDIES OF PRISTINE SULFIDES IN CM CHONDRITES IN ORDER TO UNDERSTAND THE NEBULAR FORMATION AND SUBSEQUENT COOLING HISTORIES OF SULFIDE MINERALS. THIS WORK WILL PROVIDE CONSTRAINTS ON THE THERMAL HISTORIESOF CHONDRULES PARTICULARLY TYPE IIA CHONDRULES IN THIS TWO CHONDRITE GROUP. AS PART OF THIS EFFORT WE WILL DEVELOPMENT TECHNIQUES TO CARRY OUT HIGH SPATIAL RESOLUTION TRACE ELEMENT (CHALCOPHILE) ANALYSES ON FIB SECTIONS USING THE MODIFIED SXRF BEAM LINE AT THE ADVANCED PHOTON SOURCE ARGONNE NATIONAL LABORATORY AND THE NEW NSLS II FACILITY AT BROOKHAVEN NATIONAL LABORATORY THAT WILLCOME ON LINE IN 2015.
OpenAlex ID: W3169199124
FWCI: 0.403
Cites: 79
Cited by: 6
Related to: 10