Work

When SF 5 outplays CF 3 : effects of pentafluorosulfanyl decorated scorpionates on copper

Year: 2021

Type: article

Abstract: Copper–ethylene and carbonyl complexes of the newly developed [Ph 2 B(3-(SF 5 )Pz) 2 ] − enable the study of ligand steric and electronic effects caused by the –SF 5 group (dubbed “super CF 3 ”), and a comparison to the –CF 3 bearing analogs.

Source: Chemical Science

DOI: 10.1039/d1sc04846e

Authors: Anurag Noonikara-Poyil, Alvaro Muñoz-Castro, Andrii Boretskyi, Pavel K. Mykhailiuk, H. V. Rasika Dias

Institutions: The University of Texas at Arlington, Universidad Autónoma de Chile, Taras Shevchenko National University of Kyiv, Enamine (Ukraine)

Language: English

Topic: Synthesis and characterization of novel inorganic/organometallic compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: Welch Foundation, Ministry of Education and Science of Ukraine, Taras Shevchenko National University of Kyiv, Division of Mathematical Sciences

Awards: G76353325, G8538811889