Work

Enhanced dimensionless figure-of-merit of Ca 3 Co 4 O 9 by nano-sized precursor

Year: 2021
Type: article
Abstract: Ca 3 Co 4 O 9 sample synthesized from nanometer of CaCO 3 and Co 2 O 3 sized precursor has been prepared by solid-state reaction and fast sintering by hot press method. The fast-sintering time can maintain the particle size of the nanometer. Their thermoelectric properties at high temperatures have been studied at 300–1000 K. The usage of a nano-sized precursor leads to decreased electrical resistivity, increased power factor, and would lead to huge dimensionless figure-of-merit ( Z T ) growth, respectively. The main effect is observed on thermal conductivity that is lower than the sample synthesized with micrometer precursors powder from 0.67 W mK −1 which became 0.36 W mK −1 at 973 K. The best Z T value of Ca 3 Co 4 O 9 reaches 0.51 at 973 K.
Language: English
Open Access status: bronze
OpenAlex ID: W4200162356
FWCI: 0.071
Cites: 23
Cited by: 1
Related to: 10