Work

Magnetic anisotropy of transition metal and lanthanide ions in pentagonal bipyramidal geometry

Year: 2022

Type: review

Abstract: slow relaxation of their magnetization) in order to highlight the essential chemical and structural parameters for achieving strong axial anisotropy. The use of PBP complexes to impart controlled magnetic anisotropy in polynuclear species such as SMMs or SCMs is also addressed. This review of the magnetic anisotropies associated with a pentagonal bipyramidal coordination sphere for transition metal and lanthanide ions is intended to highlight some general trends that can guide chemists towards designing a compound with specific properties.

Source: Chemical Society Reviews

DOI: 10.1039/d2cs00028h

Authors: Jean-Pascal Sutter, Virginie Béreau, Valentin Jubault, Kateryna Bretosh, Céline Pichon, Carine Duhayon

Institutions: Centre National de la Recherche Scientifique, Laboratoire de Chimie de Coordination, Université de Toulouse, Université Toulouse III - Paul Sabatier

Language: English

Topic: Magnetism in coordination complexes

Subfield: Electronic, Optical and Magnetic Materials

Field: Materials Science

Domain: Physical Sciences

Open Access status: bronze

OpenAlex ID: W4221047328

FWCI: 0.732

Cites: 179

Cited by: 79

Related to: 10