Growth mechanism, structure and thermoelectric properties of thermally evaporated Bi2(Te0.9Se0.1)3thin films
Year: 2022
Type: article
Abstract: The growth mechanism, crystal structure, and morphology of thin films with thicknesses d = 16-207 nm prepared by thermal evaporation in vacuum of p-Bi2(Te0.9Se0.1)3 polycrystal on glass substrates were studied using X-ray diffractometry and atomic force microscopy. The obtained polycrystalline thin films were single-phase and homogeneous, had a tetradymite-type structure and a unit cell parameter very close to that of Bi2(Te0.9Se0.1)3 polycrystal but, unlike the initial polycrystal, exhibited n-type conductivity. With increasing d, the grain size and roughness of the thin films increased. It was found that the predominant direction of the crystallite growth was [0 0 l], but at d larger than ~ 130 nm, along with the reflections from the (0 0 l) planes, weak reflections from other planes appeared, indicating a certain disorientation of crystallites. An increase in d led to a monotonic increase in the Seebeck coefficient, which indicated the presence of the classical size effect. The obtained data have shown that using a low-cost method of thermal evaporation in vacuum from a single source, one can grow thin Bi2(Te0.9Se0.1)3 films with partial Te -> Se substitution in Bi2Te3 of a sufficiently high quality with preferential orientation [0 0 l].
Source: Functional materials
DOI: 10.15407/fm29.01.44
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: green
OpenAlex ID: W4224116395