Work

Metastable doubly threaded [3]rotaxanes with a large macrocycle

Year: 2022

Type: article

Abstract: Multiple metastable doubly threaded [3]rotaxanes using a large 46 atom ring were prepared and fully characterized. Varying the stopper group size gave a range of interlocked stabilities in CDCl 3 from a half-life of <1 minute to ca. 6 months.

Source: Chemical Science

DOI: 10.1039/d2sc01486f

Authors: Jerald E. Hertzog, Vincent J. Maddi, Laura F. Hart, Benjamin W. Rawe, Phillip M. Rauscher, Katie M. Herbert, Eric P. Bruckner, Juan J. de Pablo, Stuart J. Rowan

Institutions: University of Chicago, Case Western Reserve University, Argonne National Laboratory

Language: English

Topic: Supramolecular Chemistry and Complexes

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: National Science Foundation, University of Chicago, Materials Research Science and Engineering Center, Harvard University, Division of Materials Research, Division of Chemistry

Awards: Materials Research Science and Engineering Center, G4657484576, Doubly-Threaded Polycatenanes and Polyrotaxanes, Synthesis of Doubly-Threaded Interlocked Macromolecules, G724762662, G8048112891, G8168854686, G8372860591, G8411689924, G935552465

OpenAlex ID: W4226174145

FWCI: 1.143

Cites: 94

Cited by: 16

Related to: 10