Work

Electrostatic vs. inductive effects in phosphine ligand donor properties and reactivity

Year: 2022

Type: article

Abstract: A detailed analysis of donor properties in solution reveals a major, even dominant, electrostatic effect from charged substituents.

Source: Chemical Science

DOI: 10.1039/d1sc04277g

Authors: Margaret L. Kelty, Andrew J. McNeece, Josh W. Kurutz, Alexander S. Filatov, John S. Anderson

Institution: University of Chicago

Language: English

Topic: Organoboron and organosilicon chemistry

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: National Science Foundation, Alfred P. Sloan Foundation, University of Chicago, National Institutes of Health, National Institute of General Medical Sciences

Awards: G1925058530, G2401083748, Graduate Research Fellowship Program (GRFP), Distal Anion Stabilization of Biologically Relevant Oxo Intermediates, Graduate Research Fellowship Program (GRFP)

OpenAlex ID: W4226312052

FWCI: 1.432

Cites: 139

Cited by: 16

Related to: 10