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Nitrous Acid Deamination of (R)-b-aminoadipic Acid

Year: 1977

Type: article

Abstract: Intramolecular participation by carboxyl group in diazotization processes has received much attention.The deamination of (R)-6-aminoadipic acid in aqueous nitrous acid affords (2)-carboxymethylbutanolide (2) with 69% net inversion.In connection with diazotization of L-glutamic acid which affords (S)-y-carboxy-y-butyrolactone -

Source: Heterocycles

DOI: 10.3987/r-1977-04-0395

Authors: Toshio Wakabayashi, Yoshinori Kato

Language: English

Topic: Cyclopropane Reaction Mechanisms

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

OpenAlex ID: W4237792955

FWCI: 0.616

Cites:

Cited by: 5

Related to: 10