Year: 2021
Type: preprint
Abstract: Experimental mechanistic studies to learn about suitable conditions for a successful photocatalytic oxidation of Breslow intermediates. Key findings a) address the effect of additives (oxidative, reductive) and assembly effects on PET and the dark reaction, b) include the experimental support of a SET + HAT sequence directly connecting the primary adduct of aldhyde and NHC and the Breslow intermediate.
Source: ChemRxiv
Authors: Jenny Phan, Julia Rehbein
Institution: University of Regensburg
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: green
OpenAlex ID: W4243257601