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Sulfamides direct radical-mediated chlorination of aliphatic C–H bonds

Year: 2019
Type: article
Abstract: Amine-anchored sulfamides direct radical-mediated chlorination of aliphatic C–H bonds. The site of C–H abstraction can be modulated by varying the sulfamide nitrogen substituents, a feature that has not been demonstrated with other substrate classes.
DOI: 10.1039/c9sc03428e
Institution: Duke University
Language: English
Field: Chemistry
Open Access status: diamond
Funders: National Science Foundation, Howard Hughes Medical Institute, U.S. Department of Education, North Carolina Biotechnology Center, Duke University, National Institutes of Health, National Institute of General Medical Sciences, Division of Chemistry
Awards: G158176174, G306402402, MRI: Acquisition of a TOF High Resolution Mass Spectrometer, GRADUATE RESEARCH FELLOWSHIP PROGRAM, Exploiting Masked Alcohols to Guide Atom-Transfer Reactions, G6062378115, G8270164139
OpenAlex ID: W2989331860
FWCI: 3.333
Cites: 63
Cited by: 54
Related to: 10