Work

[Ti(CO)4(3-BH4)] and [Ti(CO)4(5-C4H4N)]: The First Zerovalent Metal Complexes Containing 3-Borohydride and Pyrrolyl Ligands

Year: 2000

Type: article

Abstract: Tridentate binding of BH4− to a zero-valent metal center was found for the first time in [Ti(CO)4(η3-BH4)]− (shown in the picture), which was obtained from the reaction of the carbonyl metalate anion [Ti(CO)6]2− with BH3⋅THF. Displacement of the unusually labile BH4− anion by a pyrrolyl anion provided the first metal(0) pyrrolyl complex [Ti(CO)4(η5-C4H4N)]−.

Source: Angewandte Chemie International Edition

DOI: 10.1002/(sici)1521-3773(20000103)39:1<189::aid-anie189>3.0.co;2-o

Authors: Paul J. Fischer, Victor G. Young, Jr., John E. Ellis

Institution: University of Minnesota

Language: English

Topic: Organometallic Complex Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

Funder: American Chemical Society Petroleum Research Fund

OpenAlex ID: W2072597400

FWCI: 1.938

Cites: 25

Cited by: 27

Related to: 10