Work

Expanding the Scope of Palladium-Catalyzed B–N Cross-Coupling Chemistry in Carboranes

Year: 2020

Type: article

Abstract: Here we show that azide, sulfonamide, cyanate, and phosphoramidate nucleophiles can be straightforwardly cross-coupled onto the B(9) vertices of the o- and m-carborane core from readily accessible precursors without significant deboronation by-products, laying the groundwork for further study into the utility and properties of these new B-aminated carborane species.

Source: Organometallics

DOI: 10.1021/acs.organomet.0c00576

Authors: Xin Mu, Morgan Hopp, Rafal M. Dziedzic, Mary A. Waddington, Arnold L. Rheingold, Ellen M. Sletten, Jonathan C. Axtell, Alexander M. Spokoyny

Institutions: University of California, Los Angeles, University of California San Diego

Language: English

Topic: Boron Compounds in Chemistry

Subfield: Radiology, Nuclear Medicine and Imaging

Field: Medicine

Domain: Health Sciences

Open Access status: green

Funders: Camille and Henry Dreyfus Foundation, National Institute of General Medical Sciences

Awards: G1204455328, G8008881834, Bioorthogonal host-guest chemistry for tandem imaging and therapy

OpenAlex ID: W3107884970

FWCI: 2.439

Cites: 89

Cited by: 30

Related to: 10