Work

Controlling Chiral Self-Sorting in Truxene-Based Self-Assembled Cages

Year: 2022

Type: article

Abstract: Coordination driven self-assembly of achiral components, i.e., hexa-alkylated truxene ligands (L) with bis-metallic complexes (M2), afforded three chiral face-rotating stereoisomer polyhedra (M6L2). By tuning the length of the alkyl chains as well as the distance between both ligands facing each other in the self-assemblies (M6L2), one can control the diastereomeric distribution between the expected homo- and hetero-chiral structures.

Source: Inorganics

DOI: 10.3390/inorganics10070103

Authors: Amina Benchohra, Simon Séjourné, Antoine Labrunie, Liam Miller, Enzo Charbonneau, Vincent Carré, Frédéric Aubriet, Magali Allain, Marc Sallé, Sébastien Goeb

Institutions: Centre National de la Recherche Scientifique, Institut des Sciences et Technologies Moléculaires d'Angers, Université d'Angers, Laboratoire de Chimie et Physique - Approche Multi-échelle des Milieux Complexes, Réseau National de Spectrométrie de Masse FT-ICR à très haut champ, Université de Lorraine

Language: English

Topic: Supramolecular Chemistry and Complexes

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $1,675

Funders: Centre National de la Recherche Scientifique, Universite Angers

Awards: G1516814034, G2377464500

OpenAlex ID: W4286220096

FWCI: 0.464

Cites: 63

Cited by: 7

Related to: 10