Work

γ-Agostic interactions in ( Mes CCC)Fe–Mes(L) complexes

Year: 2022

Type: article

Abstract: H NMR resonance for the mesityl methyl resonances. The nature of the interaction was further investigated by density functional theory calculations, allowing rationalization of some unexpected trends and proving to be a powerful predictive tool.

Source: Chemical Communications

DOI: 10.1039/d2cc03260k

Authors: Daniel C. Najera, Marconi N. Peñas-Defrutos, Max García-Melchor, Alison R. Fout

Institutions: University of Illinois Urbana-Champaign, Universidad de Valladolid, Trinity College Dublin, Advanced Materials and BioEngineering Research

Language: English

Topic: Organometallic Complex Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

Funder: National Science Foundation

Award: Hyperpolarization Catalysts for in situ Mechanistic Studies