Synthesis and spectral characterization of Nin, Cull and znii complexes of trioxadiazamacrocycles derived from 1, 13-diamino-4, 7,1 0-trioxatridecane and benzil or 4,4' -dimethylbenzil
Year: 2011
Type: article
Abstract: Department of Chemistry, University of Rajasthan, Jaipur-302 055, Rajasthan, India E-mail: [email protected] Manuscript received 10 June 2010, revised 14 January 2011, accepted 02 February 2011 1+1 Cyclocondensation of a-diketones such as benzil, 4,4' -dimethylbenzil with I ,13-diamino-4, 7,10- trioxatridecane in the presence of NiII , CuII and znII as templates has yielded complexes of the type [NiLCI]CI, [CuL(NO3)](NO3) and [ZnLCI2) (where L = 17-membered N2O3 macrocycle). These complexes have been characterized by elemental analyses, molar conductances, FAB mass, IR, electronic and 1H NMR spectra.
Authors: R. N. Prasad, Sharma, Priyanka
Language: English
Subfield: Organic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: green
OpenAlex ID: W4298876848