Work

Electron-decoupled MAS DNP with N@C 60

Year: 2023

Type: article

Abstract: Frequency-chirped microwaves decouple electron- and 13 C-spins in magic-angle spinning N@C 60 :C 60 powder, improving DNP-enhanced 13 C NMR signal intensity by 12% for 7 s polarization, and 5% for 30 s polarization.

Source: Physical Chemistry Chemical Physics

DOI: 10.1039/d2cp04516h

Authors: Nicholas Alaniva, Edward P. Saliba, Patrick T. Judge, Erika L. Sesti, Wolfgang Harneit, Björn Corzilius, Alexander B. Barnes

Institutions: Washington University in St. Louis, ETH Zurich, Laboratory of Physical Chemistry, Massachusetts Institute of Technology, Osnabrück University, University of Rostock

Language: English

Topic: Advanced NMR Techniques and Applications

Subfield: Spectroscopy

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Funders: National Science Foundation, Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Award: Dynamic Nuclear Polarization at Room Temperature for High Sensitivity Nuclear Magnetic Resonance

OpenAlex ID: W4319058220

FWCI: 0.553

Cites: 61

Cited by: 6

Related to: 10