Work

Geometry-dependent valence tautomerism, magnetism, and electrical conductivity in 1D iron–tetraoxolene chains

Year: 2023

Type: article

Abstract: ). Meanwhile, the linear chains are more amenable to oxidative doping, leading to Robin-Day class II/III mixed-valency and an increase in electrical conductivity by nearly three orders of magnitude. While previous studies have focused on the effects of changing metal and ligand identity, this work highlights how altering the metal-ligand connectivity can be a similarly powerful tool for tuning materials properties.

Source: Chemical Science

DOI: 10.1039/d2sc06392a

Authors: Ashlyn A. Kamin, Ian P. Moseley, Jeewhan Oh, E. J. Brannan, Paige M. Gannon, Werner Kaminsky, Joseph M. Zadrozny, Dianne J. Xiao

Institutions: University of Washington, Colorado State University, Harvard University

Language: English

Topic: Organic and Molecular Conductors Research

Subfield: Electronic, Optical and Magnetic Materials

Field: Materials Science

Domain: Physical Sciences

Open Access status: diamond

Funders: National Science Foundation, U.S. Department of Energy, Arnold and Mabel Beckman Foundation, Research Corporation for Science Advancement, Harvard University, University of Washington, Office of Science, Clean Energy Institute, Division of Chemistry, Basic Energy Sciences

Awards: G1286236842, G1286251239, NEW SYNTHETIC APPROACHES TOWARDS ATOMICALLY PRECISE P–D CONJUGATED MATERIALS, G1863003419, G30714459, G3083819904, G419881185, G42916606, Purchase of an X-ray Diffractometer, G4501827968, G498139845, G5094606986, G650090426, G7977464233, G8004894364, G969889393

OpenAlex ID: W4361012895

FWCI: 0.771

Cites: 51

Cited by: 13

Related to: 10