Work

Regiodivergent sulfonylation of terminal olefins via dearomative rearrangement

Year: 2023

Type: article

Abstract: A regiodivergent transition metal-free approach towards sulfones [( E )-allylic sulfones and α-sulfonylmethyl styrenes] is reported. Solvents and temperature play a key role in the selectivity of the reaction.

Source: New Journal of Chemistry

DOI: 10.1039/d3nj03595f

Authors: Ever A. Blé-González, Stephen R. Isbel, Olatunji S. Ojo, Patrick C. Hillesheim, Matthias Zeller, Alejandro Bugarin

Institutions: Florida Gulf Coast University, The University of Texas at Arlington, Ave Maria University, Purdue University West Lafayette

Language: English

Topic: Sulfur-Based Synthesis Techniques

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

Funders: National Science Foundation, Florida Gulf Coast University, National Institutes of Health, American Chemical Society Petroleum Research Fund, National Institute of General Medical Sciences, Division of Chemistry

Awards: G1124212407, G114242917, G1167051627, Assessing Ligand vs Ligandless Catalysis to Simplify Chemical Transformations and Drug Discovery, MRI: Acquisition of an X-ray Diffractometer at Purdue University, G4267811985, G7261697988

OpenAlex ID: W4386077500

FWCI: 0.205

Cites: 48

Cited by: 2

Related to: 10