Work

Facile synthesis of multi-layer Co(OH)2/CeO2-g-C3N4 ternary synergistic heterostructure for efficient photocatalytic oxidation of NO under visible light

Year: 2023

Type: article

Abstract: In this work, we report a one-step synthesis of ternary Z-scheme Co(OH)2/CeO2-g-C3N4 (CoCe-CN) heterostructure via hydrothermal method. Owing to the modification of Co(OH)2 and CeO2, the existence of Co(OH)2 as an electron acceptor-donor center between CeO2 and g-C3N4 accelerates the electron transfer and provides extra OH- reaction pathway for photocatalytic oxidation of NO. As a result, 50CoCe-CN (Co and Ce accounting for 25% mass ratio separately) achieved a 53.5% conversion efficiency of NO at 600 ppb concentration, which is 1.82 times that of g-C3N4 under visible light. The results of the DFT analysis and element distribution of cobalt and ceria provide convincing evidence supporting the existence of a novel multi-layer structure in the CoCe-CN photocatalyst. This structure involves the loading of CeO2 and Co(OH)2 on the g-C3N4 surface, and Co(OH)2 as a co-catalyst introduced between CeO2 and g-C3N4 realizes the synergy between CeO2 and Co(OH)2 which further improve the photocatalytic properties. The higher photocatalytic efficiencies observed in the CoCe-CN photocatalysts compared to those containing only cobalt (Co-CN) or ceria (Ce-CN) provide further evidence of the synergistic effect of these two elements. This work demonstrates a more efficient and effective ternary photocatalytic system, with greater practical potential for photocatalytic oxidation of NO. NOx is considered as a harmful air pollutant in both outdoor and indoor environments， which can lead to photochemical smog and cause respiratory diseases via the exposure. Herein, a ternary heterostructure Co(OH)2/CeO2-g-C3N4 photocatalyst was fabricated using a facile ultrasonication-hydrothermal process which was found to improve the oxidation efficiency up to 53% at the NO concentration down to ppb level. In this photocatalyst of multi-layer structure, Co(OH)2 not only promotes the electronic communication between g-C3N4 and CeO2, but also provides an efficient pathway to utilize OH- to accelerate the production of •O2- and •OH.

Source: Journal of Hazardous Materials

DOI: 10.1016/j.jhazmat.2023.132744